Dating techniques of the earth
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Lava erupting earlier would come from the top of the magma chamber, and lava erupting later would come from lower down.
A number of processes could cause the parent substance to be depleted at the top of the magma chamber, or the daughter product to be enriched, both of which would cause the lava erupting earlier to appear very old according to radiometric dating, and lava erupting later to appear younger.
Oftentimes the rate of cooling occurs rapidly enough to prohibit the complete transformation of calcium-rich feldspar into sodium-rich feldspar.
In these instances, the feldspar crystals will have calcium-rich interiors surrounded by zones that are progressively richer in sodium.
Here I want to concentrate on another source of error, namely, processes that take place within magma chambers.
To me it has been a real eye opener to see all the processes that are taking place and their potential influence on radiometric dating.
Radiometric dating is largely done on rock that has formed from solidified lava.
These long time periods are computed by measuring the ratio of daughter to parent substance in a rock and inferring an age based on this ratio.
This age is computed under the assumption that the parent substance (say, uranium) gradually decays to the daughter substance (say, lead), so the higher the ratio of lead to uranium, the older the rock must be.